Optimal Design and Development of Magnetic Field Detection Sensor for AC Power Cable.

The state detection of power cables is very important to ensure the reliability of the power supply. Traditional sensors are mostly based on electric field detection. The operation is complex, and its efficiency needs to be improved. This paper optimizes the design and development of the magnetic field detection sensor for AC power cables. First, through the establishment of the magnetic field sensor model, it is determined that permalloy is the material of the magnetic core, the optimal aspect ratio of the magnetic core is 20, and the ratio of coil length to core length is 0.3. Second, the coil-simulation model is established, and it is determined that the optimal number of turns of the coil is 11,000 turns, the diameter of the enameled copper wire is 0.08 mm, and the equivalent magnetic field noise of the sensor is 0.06 pT. Finally, the amplifying circuit based on negative magnetic flux feedback is designed, the sensor is assembled, and the experimental circuit is built for the sensitivity test. The results show that the sensitivity of the magnetic field sensor is 327.6 mV/µT. The sensor designed in this paper has the advantages of small size, high sensitivity, ease of carry, and high reliability.

Curing Regime-Modulating Insulation Performance of Anhydride-Cured Epoxy Resin: A Review.

Anhydride-cured bisphenol-A epoxy resin is widely used in the support, insulation and sealing key components of electrical and electronic equipment due to their excellent comprehensive performance. However, overheating and breakdown faults of epoxy resin-based insulation occur frequently under conditions of large current carrying and multiple voltage waveforms, which seriously threaten the safe and stable operation of the system. The curing regime, including mixture ratio and combination of curing time and temperature, is an important factor to determine the microstructure of epoxy resin, and also directly affects its macro performances. In this paper, the evolution of curing kinetic models of anhydride-cured epoxy resin was introduced to determine the primary curing regime. The influences of curing regime on the insulation performance were reviewed considering various mixture ratios and combinations of curing time and temperature. The curing regime-dependent microstructure was discussed and attributed to the mechanisms of insulation performance.

Thermal Aging Evaluation of XLPE Power Cable by Using Multidimensional Characteristic Analysis of Leakage Current.

Thermal aging is a common form of cable deterioration. In this paper, the effect of thermal aging on cables is evaluated by analyzing the harmonic characteristics in cable leakage currents. Cable samples were first fabricated and subjected to accelerated thermal aging tests at 120 °C. The experimental circuits were built to test the dielectric loss factor and the AC leakage current of the cable at different aging times. Then, the improved variational modal decomposition (VMD) algorithm was used for the time-frequency analysis of the leakage current, and the relationship between thermal aging and leakage current harmonics was investigated. Thermal aging was discovered to increase the capacitance and dielectric loss factor of the cable as well as generate harmonics in the leakage current, with harmonics at 150, 450, and 650 Hz being particularly sensitive to thermal aging. The multidimensional characteristic parameters such as the time-domain, frequency-domain, and relative energy and the sample entropy of the leakage current harmonics were calculated. The results demonstrated thermal aging increased the relative energy and power spectrum energy of the harmonics and increased the disorder of the harmonic sequence.

Dielectric Property and Breakdown Strength Performance of Long-Chain Branched Polypropylene for Metallized Film Capacitors.

At high temperatures, the insulation performance of polypropylene (PP) decreases, making it challenging to meet the application requirements of metallized film capacitors. In this paper, the dielectric performance of PP is improved by long-chain branching modification and adding different kinds of nucleating agents. The added nucleating agents are organic phosphate nucleating agent (NA-21), sorbitol nucleating agent (DMDBS), rare earth nucleating agent (WBG-Ⅱ) and acylamino nucleating agent (TMB-5). The results show that the long-chain branches promote heterogeneous nucleation and inhibit the motion of molecular chains, thereby enhancing the dielectric properties at high temperatures. Nucleating agents modulate the crystalline morphology of long-chain branched polypropylene (LCBPP), which leads to a decrease in the mean free path of carriers and an increase in trap energy level and trap density. Therefore, the conductivity is reduced and the breakdown strength is improved. Among the added nucleating agents, NA-21 showed a significant improvement in the electrical properties of LCBPP films. At 125 °C, compared with PP, the breakdown strength of the modified film is increased by 26.3%, and the energy density is increased by 66.1%. This method provides a reference for improving the dielectric properties of PP.

Improved Breakdown Strength of Polypropylene Film by Polycyclic Compounds Addition for Power Capacitors.

In this paper, an improved method for the electric performance of polypropylene (PP) film was proposed to promote the safety and stability of power capacitors. Modified PP films containing three different polycyclic compounds were prepared, which showed good thermal properties and decreased DC conductivity. The DC breakdown strength of the modified PP films under both positive and negative voltage is increased compared with that of the original film. The deep traps introduced by polycyclic compounds and the decreased carrier mobility give an explanation of the decreased DC conductivity. A quantum chemistry calculation was further performed to clarify the mechanism for improving electrical performance, presenting that polycyclic compounds with a high electron affinity and low ionization energy can capture high-energy electrons, protecting the PP molecular chain from attack, and then increase the breakdown strength. It is concluded that the modified PP films by polycyclic compounds have great potential in improving the insulating properties of power capacitors.

Feature extraction and classification of surface discharges on an ice-covered insulator string during AC flashover using gray-level co-occurrence matrix.

This study focuses on the feature extraction and classification of surface discharges of ice-covered insulator strings during process of alternating current flashover. The test specimen was the five units suspension ceramic insulators, which was artificially accreted with wet-grown ice in the cold-climate room of CIGELE. Based on the IEEE Standard 1783/2009, flashover experiments were conducted on iced insulators to measure the minimum flashover voltage (VMF) and record the propagating process of surface discharges to flashover by using a high-speed video camera. The gray-level co-occurrence matrix (GLCM) method has been used to extract four parameters of arc discharge images features that characterize different stages of flashover process. The parameters are angular second moment (ASM), contrast (CON), inverse difference moment (IDM) and entropy (ENT). These statistical parameters of GLCM can be extracted to reveal the underlying properties of ice flashover on the insulator surface from the quantitative perspective. The different values of these indicators are representative of the different stages in the process of arc discharge. Once the value of quantitative indicators (ASM, CON, IDM, ENT) of surface discharges exceeds the threshold value, the higher flashover risk of iced insulators will appear. Hence, the proposed methods are helpful to understand and monitor surface discharge on iced outdoor insulator strings for preventing flashover accidents.

Effect of sPP Content on Electrical Tree Growth Characteristics in PP-Blended Cable Insulation.

This paper aims at investigating the electrical tree characteristics of isotactic polypropylene (iPP)/syndiotactic polypropylene (sPP) blends for thermoplastic cable insulation. PP blended samples with sPP contents of 0, 5, 15, 30, and 45 wt% are prepared, and electrical treeing experiments are implemented under alternating current (AC) voltage at 50, 70, and 90 °C. Experimental results show that with the incorporation of sPP increasing to 15 wt%, the inception time of electrical tree increases by 8.2%. The addition of sPP by 15% distinguishes an excellent performance in inhibiting electrical treeing, which benefits from the ability to promote the fractal dimension and lateral growth of branches. Further increase in sPP loading has a negative effect on the electrical treeing resistance of blended insulation. It is proved by DSC and POM that the addition of sPP promotes the heterogeneous crystallization the of PP matrix, resulting in an increasing density of interfacial regions between crystalline regions, which contains charge carrier traps. Charges injected from an electrode into a polymer are captured by deep traps at the interfacial regions, thus inhibiting the propagation of electrical tree. It is concluded that the modification of crystalline morphology by 15 wt% sPP addition has a great advantage in electrical treeing resistance for PP-based cable insulation.

Effect of micro-H2O and micro-O2 on the decomposition characteristics of insulating medium C3F7CN gas using molecular dynamics and transition state method.

In recent years, heptafluoroisobutyronitrile (C3F7CN) has been proved to be a potential eco-friendly insulating medium to replace sulfur hexafluoride (SF6, the strong greenhouse gas). In this paper, the effect of micro-H2O and micro-O2 on the decomposition of C3F7CN was investigated based on the reactive force field molecular dynamics (ReaxFF-MD) and transition state theory (TST). It was found that H2O obviously promoted the decomposition of C3F7CN, and new products HF, COF2, CO, and NO were generated. The influence of O2 on the C3F7CN dissociation was weaker than that of H2O, and O2 slightly promoted the C3F7CN decomposition only when 50 O2 molecules were added. The simultaneous presence of H2O and O2 promoted the decomposition of C3F7CN, the promotion of which was closed to H2O existing alone. The calculation results showed that the energy barriers of the two reactions forming COF2 were 31.38 kcal/mol and 23.85 kcal/mol, respectively, which indicated that the reactions were difficult to proceed spontaneously. The energy barrier of F + H2O → HF + OH was relatively lower than that of COF2. These values corresponded well to the ReaxFF simulation results. This study provides theoretical support for the effect of H2O and O2 on the decomposition of C3F7CN.

Non-Linear Conductivity Epoxy/SiC Composites for Emerging Power Module Packaging: Fabrication, Characterization and Application.

In this paper, SiC/epoxy resin composites containing different amounts of micro-sized SiC with different crystal morphologies were fabricated to study the effects of crystal morphology and temperature on non-linear conductivity characteristics. The research results illustrate that the ß-SiC particles can provide a higher non-linear conductivity, compared with the α-SiC particles. The presence of temperature also affected the non-linear conductivity behaviors of the epoxy/SiC composites. When the α-SiC content was low, the non-linear conductivity coefficient of the composites increased rapidly as the temperature increased, but the non-linear conductivity decreased slightly as the temperature increased when the filler concentration was large enough. To reduce the influence of the electric field concentration effect by the increase in power density on the power module packaging, the voltage sharing application of the SiC/epoxy composites was simulated by COMSOL Multiphysics (v5.2a, COMSOL Inc., Stockholm, Sweden). The results show that the composites with non-linear conductivity can reduce the electric field stress. The emerging insulation material obtained by the SiC-modified epoxy resin can effectively promote electric field distribution uniformity, and ensure the safe operation of the power module.

Molecular Structure Modulated Trap Distribution and Carrier Migration in Fluorinated Epoxy Resin.

Surface charge accumulation on epoxy insulators is one of the most serious problems threatening the operation safety of the direct current gas-insulated transmission line (GIL), and can be efficiently inhibited by the surface modification technology. This paper investigated the mechanisms of fluorination modulated surface charge behaviors of epoxy resin through quantum chemical calculation (QCC) analysis of the molecular structure. The results show that after fluorination, the surface charge dissipation process of the epoxy sample is accelerated by the introduced shallow trap sites, which is further clarified by the carrier mobility model. The electron distribution probability of the highest occupied molecular orbitals (HOMO) under positive charging and the lowest unoccupied molecular orbitals (LUMO) under negative charging shows distinctive patterns. It is illustrated that electrons are likely to aggregate locally around benzenes for the positively charged molecular structure, while electrons tend to distribute all along the epoxy chain under negatively charging. The calculated results verify that fluorination can modulate surface charge behaviors of epoxy resin through redesigning its molecular structure, trap distribution and charging patterns.

Coupling Effect of Molecular Chain Displacement and Carrier Trap Characteristics on DC Breakdown of HDPE/LDPE Blend Insulation.

This work focuses on the coupling effect of molecular chain displacement and trap characteristics on direct current (DC) breakdown properties of high density/low density polyethylene (HDPE/LDPE) blend insulation. Frequency domain spectroscopy (FDS) and isothermal discharge current (IDC) are used to characterize the dielectric relaxation and trap characteristics of HDPE/LDPE blends. A DC breakdown model is proposed to reveal the mechanisms of the molecular chain displacement and carrier trap on the DC breakdown strength. The dielectric relaxation α and δ present segmental motions and thermal ion polarization behaviours of HDPE/LDPE blends, respectively. α dielectric relaxation strength ( Δεα) increases as the amount of HDPE increases from 0 to 5 wt%, and then declines with a further increase of HDPE content to 20 wt%. According to the velocity equation, the increase of Δεα will increase the molecular chain displacement, resulting in a larger free volume, which will provide electrons with larger free path λ to form hot electrons. A positive correlation exists between the activation energy of the dielectric relaxation process δ and trap density, and the increase of δ dielectric relaxation strength (Δεδ) will adversely affect the breakdown strength of the specimen. HDPE/LDPE blends with 15 wt% HDPE content have lower Δεα and lowest Δεδ, which decreases the mean free path λ of molecular chain and thermal ion polarization. At the same time, it has the highest deep trap density, thus increasing the probability of hot electrons being captured and improving the DC breakdown strength. It is concluded the breakdown of the dielectric is synergistically affected by the molecular chain displacement and carrier trap.

Synthesis of CoTe nanowires: a new electrode material for supercapacitor with high stability and high performance.

Highly dispersed CoTe electrode material were successfully prepared by using a facile one-step solvothermal process without any surfactants. Compared with the conventional hydrothermally prepared irregularly-shaped CoTe, a regular nanowire-formed CoTe can be obtained by a solvothermal process using ethylene glycol as a solvent. The prepared CoTe nanowire electrode can exhibit a relatively high specific capacity of 643.6 F g-1 at a current density of 1 A g-1 and remarkable cyclic stability with 76.9% of its specific capacitance retention after 5000 cycles at a high current density of 5 A g-1. Besides, even at the high current density of 20 A g-1, the specific capacitance of CoTe nanowire electrode still has 90.2% retention relative to 1 A g-1, showing an excellent rate performance. In order to enlarge the potential window to increase the energy density, an asymmetric supercapacitor (ASC) is assembled by applying CoTe nanowires and activated carbon as the positive electrode and the negative electrode in 3 M KOH, which can enlarge the operating voltage to as high as 1.6 V, and shows a specific capacity of 92.5 F g-1 with an energy density of 32.9 Wh kg-1 and power density of 800.27 W kg-1 at 1 A g-1, and even after 5000 cycles of charge/discharge at 5 A g-1, the ASC still retains 90.5% of its initial specific capacitance, showing excellent cycle stability.

Inhibition Effect of Graphene Nanoplatelets on Electrical Degradation in Silicone Rubber.

Silicone rubber (SIR) is widely used as an insulation material in high voltage cable accessories. Electrical tree is a typical electrical degradation and is easily initiated because of the distorted electric field. In this study, graphene nanoplatelets at contents of 0.001-0.010 wt % (0.00044-0.00436 vol %) were added into SIR to improve the electrical tree inhibiting ability. Scanning electron microscopy, conductivity and surface potential decay tests were conducted to analyze the characteristics of graphene/SIR nanocomposites. The typical electrical treeing experiment was employed to observe the electrical tree inhibition of graphene in SIR. The results show that graphene nanoplatelets were well dispersed in SIR. The conductivity was higher after the addition of graphene nanoplatelets, and the trap distribution was affected by graphene nanoplatelets. The tree was changed from a bush-branch structure to a bush structure after the addition of graphene. Tree inception voltage improved and reached the highest mean value at 0.003 wt %. The tree length was inhibited at 0.001 to 0.007 wt % and the lowest tree length occurred at 0.005 wt %.

Inhibition Effect of Graphene on Space Charge Injection and Accumulation in Low-Density Polyethylene.

Space charge injection and accumulation is attracting much attention in the field of dielectric insulation especially for electronic devices, power equipment and so on. This paper proposes using the inhibition effect of graphene for the injection and accumulation of space charge in low-density polyethylene (LDPE). Scanning electron microscope (SEM) and transmission electron microscopy (TEM) images were employed to observe the dispersion of graphene with a two-dimensional structure in LDPE. The time-dependent space charge dynamic behaviors of graphene/LDPE nanocomposites with the filler content of 0, 0.003, 0.005, 0.007 and 0.01 wt % were characterized by the pulsed electro-acoustic (PEA) test at 40, 60 and 80 °C, and the charge mobility was evaluated by its depolarization processes. The experimental results show that for the undoped LDPE film, large amounts of space charges were injected from the electrodes into samples, especially at 60 and 80 °C. The graphene/LDPE nanocomposites with a filler content of 0.005 wt % could markedly suppress the space charge injection and accumulation even at 80 °C, which is attributed to the large quantities of graphene-polymer in interface regions. These interface regions introduced numbers of deep trap sites within the forbidden band of nanocomposites, which can reduce the de-trapping rate of charges and suppress the space charge accumulation in the polymer bulks. The graphene/LDPE nanocomposites are suggested for dielectric applications, intending the inhibition of space charge injection and accumulation.

Understanding Trap Effects on Electrical Treeing Phenomena in EPDM/POSS Composites.

POSS (polyhedral oligomeric silsesquioxane) provides an interesting alternative nano-silica and has the potential of superior dielectric properties to restrain electrical degradation. By incorporating POSS into EPDM to suppress electrical tree, one of precursors to dielectric failure, is promising to improve the lifetime of insulation materials. This paper focuses on the electrical treeing phenomena in EPDM/OVPOSS (ethylene propylene diene monomer/octavinyl-POSS) composites based on their physicochemical properties and trap distributions. ATR-IR and SEM characteristics are investigated to observe the chemical structure and physical dispersion of EPDM/OVPOSS composites. Electrical treeing characteristics are studied by the needle-plane electrode, and the trap level distributions are characterized by surface potential decay (SPD) tests. The results show that the 3 wt% EPDM/OVPOSS is more effective to restrain the electrical tree growth than the neat EPDM in this paper. It is indicated that the EPDM/OVPOSS with a filler content of 3 wt% introduces the largest energy level and trap density of deep trapped charges, which suppress the transportation of charge carriers injected from the needle tip and further prevent the degradation of polymer molecules. The polarity effects are obvious during the electrical treeing process, which is dependent on the trap level differences between positive and negative voltage.

Surface Layer Fluorination-Modulated Space Charge Behaviors in HVDC Cable Accessory.

Space charges tend to accumulate on the surface and at the interface of ethylene⁻propylene⁻diene terpolymer (EPDM), serving as high voltage direct current (HVDC) cable accessory insulation, which likely induces electrical field distortion and dielectric breakdown. Direct fluorination is an effective method to modify the surface characteristics of the EPDM without altering the bulk properties too much. In this paper, the surface morphology, hydrophobic properties, relative permittivity, and DC conductivity of the EPDM before and after fluorination treatment were tested. Furthermore, the surface and interface charge behaviors in the HVDC cable accessory were investigated by the pulsed electroacoustic (PEA) method, and explained from the point of view of trap distribution. The results show that fluorination helps the EPDM polymer obtain lower surface energy and relative permittivity, which is beneficial to the interface match in composite insulation systems. The lowest degree of space charge accumulation occurs in EPDM with 30 min of fluorination. After analyzing the results of the 3D potentials and the density of states (DOS) behaviors in EPDM before and after fluorination, it can be found that fluorination treatment introduces shallower electron traps, and the special electrostatic potential after fluorination can significantly suppress the space charge accumulation at the interface in the HVDC cable accessory.

Trap Modulated Charge Carrier Transport in Polyethylene/Graphene Nanocomposites.

The role of trap characteristics in modulating charge transport properties is attracting much attentions in electrical and electronic engineering, which has an important effect on the electrical properties of dielectrics. This paper focuses on the electrical properties of Low-density Polyethylene (LDPE)/graphene nanocomposites (NCs), as well as the corresponding trap level characteristics. The dc conductivity, breakdown strength and space charge behaviors of NCs with the filler content of 0 wt%, 0.005 wt%, 0.01 wt%, 0.1 wt% and 0.5 wt% are studied, and their trap level distributions are characterized by isothermal discharge current (IDC) tests. The experimental results show that the 0.005 wt% LDPE/graphene NCs have a lower dc conductivity, a higher breakdown strength and a much smaller amount of space charge accumulation than the neat LDPE. It is indicated that the graphene addition with a filler content of 0.005 wt% introduces large quantities of deep carrier traps that reduce charge carrier mobility and result in the homocharge accumulation near the electrodes. The deep trap modulated charge carrier transport attributes to reduce the dc conductivity, suppress the injection of space charges into polymer bulks and enhance the breakdown strength, which is of great significance in improving electrical properties of polymer dielectrics.